Reconciling atmospheric CO2, weathering, and calcite compensation depth across the Cenozoic.

The Cenozoic era (66 to 0 million years) is marked by long-term aberrations in carbon cycling and large climatic shifts, some of which challenge the current understanding of carbon cycle dynamics. Here, we investigate possible mechanisms responsible for the observed long-term trends by using a novel approach that features a full-fledged ocean carbonate chemistry model. Using a compilation of pCO2, pH, and calcite compensation depth (CCD) observational evidence and a suite of simulations, we reconcile long-term Cenozoic climate and CCD trends. We show that the CCD response was decoupled from changes in silicate and carbonate weathering rates, challenging the continental uplift hypothesis. The two dominant mechanisms for decoupling are shelf-basin carbonate burial fractionation combined with proliferation of pelagic calcifiers. The temperature effect on remineralization rates of marine organic matter also plays a critical role in controlling the carbon cycle dynamics, especially during the warmer periods of the Cenozoic.

Solar System chaos and the Paleocene-Eocene boundary age constrained by geology and astronomy.

Astronomical calculations reveal the Solar System's dynamical evolution, including its chaoticity, and represent the backbone of cyclostratigraphy and astrochronology. An absolute, fully calibrated astronomical time scale has hitherto been hampered beyond ~50 million years before the present (Ma) because orbital calculations disagree before that age. Here, we present geologic data and a new astronomical solution (ZB18a) showing exceptional agreement from ~58 to 53 Ma. We provide a new absolute astrochronology up to 58 Ma and a new Paleocene-Eocene boundary age (56.01 ± 0.05 Ma). We show that the Paleocene-Eocene Thermal Maximum (PETM) onset occurred near a 405-thousand-year (kyr) eccentricity maximum, suggesting an orbital trigger. We also provide an independent PETM duration (170 ± 30 kyr) from onset to recovery inflection. Our astronomical solution requires a chaotic resonance transition at ~50 Ma in the Solar System's fundamental frequencies.

Plate tectonic controls on atmospheric CO2 levels since the Triassic.

Climate trends on timescales of 10s to 100s of millions of years are controlled by changes in solar luminosity, continent distribution, and atmosphere composition. Plate tectonics affect geography, but also atmosphere composition through volcanic degassing of CO2 at subduction zones and midocean ridges. So far, such degassing estimates were based on reconstructions of ocean floor production for the last 150 My and indirectly, through sea level inversion before 150 My. Here we quantitatively estimate CO2 degassing by reconstructing lithosphere subduction evolution, using recent advances in combining global plate reconstructions and present-day structure of the mantle. First, we estimate that since the Triassic (250-200 My) until the present, the total paleosubduction-zone length reached up to ∼200% of the present-day value. Comparing our subduction-zone lengths with previously reconstructed ocean-crust production rates over the past 140 My suggests average global subduction rates have been constant, ∼6 cm/y: Higher ocean-crust production is associated with longer total subduction length. We compute a strontium isotope record based on subduction-zone length, which agrees well with geological records supporting the validity of our approach: The total subduction-zone length is proportional to the summed arc and ridge volcanic CO2 production and thereby to global volcanic degassing at plate boundaries. We therefore use our degassing curve as input for the GEOCARBSULF model to estimate atmospheric CO2 levels since the Triassic. Our calculated CO2 levels for the mid Mesozoic differ from previous modeling results and are more consistent with available proxy data.

Long-term legacy of massive carbon input to the Earth system: Anthropocene versus Eocene.

Over the next few centuries, with unabated emissions of anthropogenic carbon dioxide (CO2), a total of 5000 Pg C may enter the atmosphere, causing CO2 concentrations to rise to approximately 2000 ppmv, global temperature to warm by more than 8(°)C and surface ocean pH to decline by approximately 0.7 units. A carbon release of this magnitude is unprecedented during the past 56 million years-and the outcome accordingly difficult to predict. In this regard, the geological record may provide foresight to how the Earth system will respond in the future. Here, we discuss the long-term legacy of massive carbon release into the Earth's surface reservoirs, comparing the Anthropocene with a past analogue, the Palaeocene-Eocene Thermal Maximum (PETM, approx. 56 Ma). We examine the natural processes and time scales of CO2 neutralization that determine the atmospheric lifetime of CO2 in response to carbon release. We compare the duration of carbon release during the Anthropocene versus PETM and the ensuing effects on ocean acidification and marine calcifying organisms. We also discuss the conundrum that the observed duration of the PETM appears to be much longer than predicted by models that use first-order assumptions. Finally, we comment on past and future mass extinctions and recovery times of biotic diversity.

Time-dependent climate sensitivity and the legacy of anthropogenic greenhouse gas emissions.

Climate sensitivity measures the response of Earth's surface temperature to changes in forcing. The response depends on various climate processes that feed back on the initial forcing on different timescales. Understanding climate sensitivity is fundamental to reconstructing Earth's climatic history as well as predicting future climate change. On timescales shorter than centuries, only fast climate feedbacks including water vapor, lapse rate, clouds, and snow/sea ice albedo are usually considered. However, on timescales longer than millennia, the generally higher Earth system sensitivity becomes relevant, including changes in ice sheets, vegetation, ocean circulation, biogeochemical cycling, etc. Here, I introduce the time-dependent climate sensitivity, which unifies fast-feedback and Earth system sensitivity. I show that warming projections, which include a time-dependent climate sensitivity, exhibit an enhanced feedback between surface warming and ocean CO2 solubility, which in turn leads to higher atmospheric CO2 levels and further warming. Compared with earlier studies, my results predict a much longer lifetime of human-induced future warming (23,000-165,000 y), which increases the likelihood of large ice sheet melting and major sea level rise. The main point regarding the legacy of anthropogenic greenhouse gas emissions is that, even if the fast-feedback sensitivity is no more than 3 K per CO2 doubling, there will likely be additional long-term warming from slow climate feedbacks. Time-dependent climate sensitivity also helps explaining intense and prolonged warming in response to massive carbon release as documented for past events such as the Paleocene-Eocene Thermal Maximum.

The geological record of ocean acidification.

Ocean acidification may have severe consequences for marine ecosystems; however, assessing its future impact is difficult because laboratory experiments and field observations are limited by their reduced ecologic complexity and sample period, respectively. In contrast, the geological record contains long-term evidence for a variety of global environmental perturbations, including ocean acidification plus their associated biotic responses. We review events exhibiting evidence for elevated atmospheric CO(2), global warming, and ocean acidification over the past ~300 million years of Earth's history, some with contemporaneous extinction or evolutionary turnover among marine calcifiers. Although similarities exist, no past event perfectly parallels future projections in terms of disrupting the balance of ocean carbonate chemistry-a consequence of the unprecedented rapidity of CO(2) release currently taking place.